Poly[[diaquadeca-μ-cyanido-hexacyanidobis(4-cyanopyridine)di-μ-pyrimidine-tricopper(II)ditungsten(V)] dihydrate]

In the polymeric title compound, {[Cu3W2(CN)16(C4H4N2)2(C6H4N2)2(H2O)2]·2H2O}n, the coordination geometry of W is an eight-coordinated bicapped trigonal prism. Five of the CN groups of [W(CN)8] are bridged to Cu ions. The coordination geometries of the Cu atoms are each pseudo-octahedral; o...

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Bibliographic Details
Main Authors: Souhei Kaneko, Yoshihide Tsunobuchi, Koji Nakabayashi, Shin-ichi Ohkoshi
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808032947