[2 × 2] Molecular Grids of Ni(II) and Zn(II) with Redox-Active 1,4-Pyrazine-Bis(thiosemicarbazone) Ligands

[2 × 2] Molecular Grids of Ni(II) and Zn(II) with Redox-Active 1,4-Pyrazine-Bis(thiosemicarbazone) Ligands

Tetranuclear complexes [M4(LR)4] with M = Ni(II) or Zn(II), with a [2 × 2] grid-type structure, were assembled in good yields and purity from the easily accessible but unprecedented pyrazine-bridged bis(thiosemicarbazone) protoligands (ligand precursors) H2LR (1,4-pyrazine-2,5-bis(R-carbal...

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Bibliographic Details
Main Authors: Natalia Arefyeva, Aaron Sandleben, Alexander Krest, Ulrich Baumann, Mathias Schäfer, Maxim Kempf, Axel Klein
Format: Article
Language:English
Published: MDPI AG 2018-05-01
Series:Inorganics
Subjects:
bis(thiosemicarbazone)
1,4-pyrazine
supramolecular chemistry
mass spectrometry
electrochemistry
Online Access:http://www.mdpi.com/2304-6740/6/2/51

Internet

http://www.mdpi.com/2304-6740/6/2/51

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