Spin-Singlet Transition in the Magnetic Hybrid Compound from a Spin-Crossover Fe(III) Cation and π-Radical Anion

Spin-Singlet Transition in the Magnetic Hybrid Compound from a Spin-Crossover Fe(III) Cation and π-Radical Anion

To develop a new spin-crossover functional material, a magnetic hybrid compound [Fe(qsal)2][Ni(mnt)2] was designed and synthesized (Hqsal = N-(8-quinolyl)salicylaldimine, mnt = maleonitriledithiolate). The temperature dependence of magnetic susceptibility suggested the coexistence of the high-spin (...

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Bibliographic Details
Main Authors: Kazuyuki Takahashi, Takahiro Sakurai, Wei-Min Zhang, Susumu Okubo, Hitoshi Ohta, Takashi Yamamoto, Yasuaki Einaga, Hatsumi Mori
Format: Article
Language:English
Published: MDPI AG 2017-08-01
Series:Inorganics
Subjects:
spin-crossover
π-radical
spin transition
spin-singlet formation
π-stacking interaction
magnetic correlation
Fe(III) complex
Ni dithiolene complex
Online Access:https://www.mdpi.com/2304-6740/5/3/54

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https://www.mdpi.com/2304-6740/5/3/54

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