Kinetic fractionation of gases by deep air convection in polar firn
A previously unrecognized type of gas fractionation occurs in firn air columns subjected to intense convection. It is a form of kinetic fractionation that depends on the fact that different gases have different molecular diffusivities. Convective mixing continually disturbs diffusive equilibrium, an...
Main Authors: | , , , , , , , |
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Format: | Article |
Language: | English |
Published: |
Copernicus Publications
2013-11-01
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Series: | Atmospheric Chemistry and Physics |
Online Access: | http://www.atmos-chem-phys.net/13/11141/2013/acp-13-11141-2013.pdf |