Kinetic fractionation of gases by deep air convection in polar firn

A previously unrecognized type of gas fractionation occurs in firn air columns subjected to intense convection. It is a form of kinetic fractionation that depends on the fact that different gases have different molecular diffusivities. Convective mixing continually disturbs diffusive equilibrium, an...

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Bibliographic Details
Main Authors: K. Kawamura, J. P. Severinghaus, M. R. Albert, Z. R. Courville, M. A. Fahnestock, T. Scambos, E. Shields, C. A. Shuman
Format: Article
Language:English
Published: Copernicus Publications 2013-11-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/13/11141/2013/acp-13-11141-2013.pdf