Oxidative Aromatization of 4,7-Dihydro-6-nitroazolo[1,5-a]pyrimidines: Synthetic Possibilities and Limitations, Mechanism of Destruction, and the Theoretical and Experimental Substantiation

Oxidative Aromatization of 4,7-Dihydro-6-nitroazolo[1,5-a]pyrimidines: Synthetic Possibilities and Limitations, Mechanism of Destruction, and the Theoretical and Experimental Substantiation

The reaction tolerance of the multicomponent process between 3-aminoazoles, 1-morpholino-2-nitroalkenes, and aldehydes was studied. The main patterns of this reaction have been established. Conditions for the oxidation of 4,7-dihydro-6-nitroazolo[1,5-a]pyrimidines were selected. Previous claims that...

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Bibliographic Details
Main Authors: Daniil N. Lyapustin, Evgeny N. Ulomsky, Ilya A. Balyakin, Alexander V. Shchepochkin, Vladimir L. Rusinov, Oleg N. Chupakhin
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Molecules
Subjects:
azolo[1,5-a]pyrimidines
nitro-synthons
oxidation
oxidative destruction
synthesis of heterocycles
multicomponent reactions
Online Access:https://www.mdpi.com/1420-3049/26/16/4719

Internet

https://www.mdpi.com/1420-3049/26/16/4719

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