On the Physical Meaning of the Isothermal Titration Calorimetry Measurements in Calorimeters with Full Cells

We have performed a detailed study of the thermodynamics of the titration Process in an isothermal titration calorimeter with full cells. We show that the relationship between the enthalpy and the heat measured is better described in terms of the equation ΔH = Winj + Q (where Winj is the work necess...

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Bibliographic Details
Main Authors: Jean-Pierre E. Grolier, Jose Manuel del Río
Format: Article
Language:English
Published: MDPI AG 2009-12-01
Series:International Journal of Molecular Sciences
Subjects:
ITC
Online Access:http://www.mdpi.com/1422-0067/10/12/5296/