C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni(II) complexes with chlorophosphines

This manuscript reports successful C-H nickellation of the aryl phosphinites (i-Pr2P(O-aryl) derived from un-substituted/substituted phenols: C6H5OH, 4-R-C6H4OH (R = F, MeO). Nickellation was observed with the phosphinites at an ortho-C-H position to generate Br-bridged dimers [{κP,κC-(i-Pr)2PO-aryl...

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Bibliographic Details
Main Authors: Aqsa Habib, Sharon Riaz, Ishaq Ahmad, Dure Najaf Iqbal, Shagufta Kamal
Format: Article
Language:English
Published: Elsevier 2021-02-01
Series:Journal of Saudi Chemical Society
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610320301678