Poly[[diaquadeca-μ2-cyanido-κ20C:N-hexacyanido-κ6C-bis(μ2-5-methylpyrimidine-κ2N:N′)bis(5-methylpyrimidine-κN)tricopper(II)ditungstate(V)] dihydrate]
In the title complex, {[Cu3[W(CN)8]2(C5H6N2)4(H2O)2]·2H2O}n, the coordination polyhedron of the eight-coordinated WV atom is a bicapped trigonal prism, in which five CN groups are bridged to CuII ions, and the other three CN groups are terminally bound. Two of the CuII ions lie on a centre of invers...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2014-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814000166 |