Direct determination of absolute stereochemistry of α-methylselenocysteine using the Mosher method

Mosher amides of α-methylselenocysteine were synthesized to determine the absolute stereochemistry of the sterically hindered α-carbon utilizing 1H, 13C, 19F, and 77Se NMR spectroscopies. After analysis of these spectra using the established Mosher method, the stereochemistry of the α-carbon was det...

Full description

Bibliographic Details
Main Authors: Robert J. Wehrle, Douglas R. Powell, Douglas S. Masterson
Format: Article
Language:English
Published: Elsevier 2021-01-01
Series:Results in Chemistry
Subjects:
NMR
Online Access:http://www.sciencedirect.com/science/article/pii/S2211715621000199