Novel neutral iron(II) isocyanide maleonitrile dithiolate [Fe(S2C2(CN)2)(t-BuNC) 4] compound

Novel neutral iron(II) isocyanide maleonitrile dithiolate [Fe(S2C2(CN)2)(t-BuNC) 4] compound

FeBr2 reacts with the S2C2(CN)2(2-) ion (1:1 ratio) in the presence of an excess of t-BuNC in THF to give the mixed ligand [Fe(S2C2(CN)2)(t-BuNC) 4] compound. This neutral product with a formal oxidation state of two for the iron atom was characterized by conductivity measurements, and, i.r., Mössba...

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Bibliographic Details
Main Authors: Milton K. Morigaki, Elias M. da Silva, Carlos V. P. de Melo, Carlos Larica, Armando Biondo, Jair C. C. Freitas, Gilson H. M. Dias, Holgadinei R. Ribeiro
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2004-02-01
Series:Química Nova
Subjects:
iron (II)
isocyanide
dithiolate
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000100016

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000100016

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