Crystal structure of acetonitrile[η6-1-methyl-4-(1-methylethyl)benzene][1-(pyrimidin-2-yl)-3H-indol-1-ium-2-yl-κ2N,C]ruthenium(II) bis(hexafluoridoantimonate)

Crystal structure of acetonitrile[η6-1-methyl-4-(1-methylethyl)benzene][1-(pyrimidin-2-yl)-3H-indol-1-ium-2-yl-κ2N,C]ruthenium(II) bis(hexafluoridoantimonate)

In the title compound, [Ru(C10H14)(C12H9N3)(CH3CN)][SbF6]2, the ruthenium(II) cation is η6-coordinated by the para-cymene ligand with a Ru–centroid(η6-benzene) distance of 1.746 (2) Å. Furthermore, ruthenium coordinations to the C and N atoms of the pyrimidyl indole ligand are found to be 1.986 (4)...

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Bibliographic Details
Main Authors: Carina Sollert, Andreas Orthaber, Lukasz T. Pilarski
Format: Article
Language:English
Published: International Union of Crystallography 2015-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclometalated RuII
pyrimidyl-3H-indole
para-cymene
C—H...F hydrogen bonds
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015016710

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http://scripts.iucr.org/cgi-bin/paper?S2056989015016710

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