Properties of Mn2+ and Π-Electron Spin Systems Probed by 1H and 13C NMR in the Organic Conductor κ-(BETS)2Mn[N(CN)2]3

Properties of Mn2+ and Π-Electron Spin Systems Probed by 1H and 13C NMR in the Organic Conductor κ-(BETS)2Mn[N(CN)2]3

Properties of the spin systems of the localized 3d Mn2+ ions and the conduction π electrons in quasi-two-dimensional organic conductor κ-(BETS)2Mn[N(CN)2]3 were accessed using 1H and 13C NMR in order to find their relation to the metal-insulator transition which occurs at ∼23 K. The transition of th...

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Bibliographic Details
Main Authors: Eduard B. Yagubskii, Nataliya D. Kushch, Sergey V. Simonov, Leokadiya V. Zorina, Megumi Kobayashi, Hiroshi M. Yamamoto, Reizo Kato, Oleg M. Vyaselev
Format: Article
Language:English
Published: MDPI AG 2012-04-01
Series:Crystals
Subjects:
organic metals
pi-d interactions
spin order
antiferromagnetism
metal-insulator transition
NMR
Online Access:http://www.mdpi.com/2073-4352/2/2/224

Internet

http://www.mdpi.com/2073-4352/2/2/224

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