NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY

NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY

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On allowing DABCOH2(HC2O4)2 to react with transition metal dihalides in ethanol, a new series of complexes of general formula M(oxalate)2 DABCOH22+. nDABCOH22+.2X- (n=1/2;1) have been obtained. When (n=1) a dimeric structure is suggested, the two monomeric species being hold together by biprotonate...

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Bibliographic Details
Main Authors: MAMADOU NDIAYE, ABDOULAYE SAMB, LIBASSE DIOP
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017-09-01
Series:Journal of Engineering Studies and Research
Subjects:
fullerene
dimeric or infinite chain structures
hydrogen bonds
monochelating ligand
octahedral or square planar environments
Online Access:http://www.jesr.ub.ro/1/article/view/77

Internet

http://www.jesr.ub.ro/1/article/view/77

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