[Cr3O(CH3COO)6(H2O)3]NO3⋅HNO3⋅H2O, TRIAQUA-HEXAKIS(μ- ACETATO)-μ3-OXO-TRICHROMIUM(III) NITRATE NITRIC ACID SOLVATE MONOHYDRATE

[Cr3O(CH3COO)6(H2O)3]NO3⋅HNO3⋅H2O, TRIAQUA-HEXAKIS(μ- ACETATO)-μ3-OXO-TRICHROMIUM(III) NITRATE NITRIC ACID SOLVATE MONOHYDRATE

Reaction in methanol solution of the trinuclear ‘basic’ chromium(III) acetate with Pr(NO3)3⋅5H2O and further extraction by chloroform-acetone mixture led to the formation of novel unusual [Cr3O(CH3COO)6(H2O)3]NO3⋅HNO3⋅H2O (1) cluster with one “free” molecule of nitric acid. Complex 1 crystallizes in...

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Bibliographic Details
Main Authors: Marco Bettinelli, Adolfo Speghini, Gabriele Bocelli, Olesea Gherco, Valeriu Mereacre, Denis Prodius, Constantin Turta
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2006-06-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
Chromium carboxylate
Polynuclear complex
UV-Vis
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/AA-0013_088.pdf

Internet

http://www.cjm.asm.md/sites/default/files/article_files/AA-0013_088.pdf

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