Aqueous-phase oligomerization of methyl vinyl ketone through photooxidation – Part 2: Development of the chemical mechanism and atmospheric implications

Laboratory experiments of efficient oligomerization from methyl vinyl ketone (MVK) in the bulk aqueous phase were simulated in a box model. Kinetic data are applied (if known) or fitted to the observed MVK decay and oligomer mass increase. Upon model sensitivity studies, in which unconstrained rate...

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Bibliographic Details
Main Authors: B. Ervens, P. Renard, S. Tlili, S. Ravier, J.-L. Clément, A. Monod
Format: Article
Language:English
Published: Copernicus Publications 2015-08-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/15/9109/2015/acp-15-9109-2015.pdf