Crystal structure of [1,1′′′-bis(pyrimidin-2-yl)-4,4′:2′,2′′:4′′,4′′′-quaterpyridine-1,1′′′-diium-κ2N1′,N1′′]bis[2-(pyridin-2-yl)phenyl-κ2N,C1]iridium(III) tris(hexafluoridophosphate) acetonitrile trisolvate

Crystal structure of [1,1′′′-bis(pyrimidin-2-yl)-4,4′:2′,2′′:4′′,4′′′-quaterpyridine-1,1′′′-diium-κ2N1′,N1′′]bis[2-(pyridin-2-yl)phenyl-κ2N,C1]iridium(III) tris(hexafluoridophosphate) acetonitrile trisolvate

In the title compound, [Ir(C11H8N)2(C28H20N8)](PF6)3·3CH3CN or [IrIII(ppy)2{(2-pym)2qpy2+}](PF6)3·3CH3CN (ppy = deprotonated 2-phenylpyridine, pym = pyrimidyl and qpy = 4,4′:2′,2′′:4′′,4′′′-quaterpyridyl), the Ir3+ cation is coordinated by two C atoms and four N atoms in a slightly distorted octahed...

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Bibliographic Details
Main Authors: Benjamin J. Coe, Martyn K. Peers, James Raftery, Nigel S. Scrutton
Format: Article
Language:English
Published: International Union of Crystallography 2015-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iridium(III)
cyclometalated
4,4′:2′,2′′:4′′,4′′′-quaterpyridyl ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015012463

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989015012463

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