Positional Isomerism in the N^N Ligand: How Much Difference Does a Methyl Group Make in [Cu(P^P)(N^N)]<sup>+</sup> Complexes?

Positional Isomerism in the N^N Ligand: How Much Difference Does a Methyl Group Make in [Cu(P^P)(N^N)]<sup>+</sup> Complexes?

The synthesis and structural characterization of 5,6′-dimethyl-2,2′-bipyridine (5,6′-Me<sub>2</sub>bpy) are reported, along with the preparations and characterizations of [Cu(POP)(5,6′-Me<sub>2</sub>bpy)][PF<sub>6</sub>] and [Cu(xantphos)(5,6′-Me<sub>2</s...

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Bibliographic Details
Main Authors: Fabian Brunner, Alessandro Prescimone, Edwin C. Constable, Catherine E. Housecroft
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Molecules
Subjects:
copper(I)
bisphosphane
2,2′-bipyridine
X-ray crystallography
photoluminescence
heteroleptic coordination compounds
Online Access:https://www.mdpi.com/1420-3049/25/12/2760

Internet

https://www.mdpi.com/1420-3049/25/12/2760

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