A new approach towards synthesis of benzo[b]fluorene core

New approach towards synthesis of  benzo[b]fluorene core is described.  The model compound, 10-methoxy-11H-benzo[b]fluoren-11-one was prepared in five steps starting from dibenzylmalonic acid.  The key step was the metal catalyzed rearrangement of 3,3’-dihalo-2,2’-spirobiindan-1,1’-dione. The choice...

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Bibliographic Details
Main Author: Jane B. Bogdanov
Format: Article
Language:English
Published: Society of Chemists and Technologists of Macedonia 2014-09-01
Series:Macedonian Journal of Chemistry and Chemical Engineering
Subjects:
Online Access:https://mjcce.org.mk/index.php/MJCCE/article/view/495