Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines

Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines

The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(η6-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes is a research topic that is still being intensively developed. This article focuses on selected aspects of thi...

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Bibliographic Details
Main Authors: Jiří Václavík, Petr Šot, Jan Pecháček, Beáta Vilhanová, Ondřej Matuška, Marek Kuzma, Petr Kačer
Format: Article
Language:English
Published: MDPI AG 2014-05-01
Series:Molecules
Subjects:
ruthenium
asymmetric hydrogenation
imine
ligand
sulfonyl
arene
DFT
Online Access:http://www.mdpi.com/1420-3049/19/6/6987

Internet

http://www.mdpi.com/1420-3049/19/6/6987

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