Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV)

Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV)

The title compound, [ZrW(C5H5)2(C2H3O)Cl(CO)5] or [W(CO)5C(CH3)OZr(C5H5)2Cl], consists of two metal centres, with a (tungsten pentacarbonyl)oxymethylcarbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the molecule are related by a crystallographic mirror...

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Bibliographic Details
Main Authors: Stephanie Cronje, Gert J. Kruger, Nyambeni Luruli, Arno Neveling, Catharine Esterhuysen
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808028006

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http://scripts.iucr.org/cgi-bin/paper?S1600536808028006

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