Synthesis and crystal structure of 1,1′-bis{[4-(pyridin-2-yl)-1,2,3-triazol-1-yl]methyl}ferrocene, and its complexation with CuI

Synthesis and crystal structure of 1,1′-bis{[4-(pyridin-2-yl)-1,2,3-triazol-1-yl]methyl}ferrocene, and its complexation with CuI

The title compound, [Fe(C13H11N4)2], was synthesized starting from 1,1′-ferrocenedicarboxylic acid in a three-step reaction sequence. The dicarboxylic acid was reduced to 1,1′-ferrocenedimethanol using LiAlH4 and subsequently converted to 1,1′-bis(azidomethyl)ferrocene in the presence of NaN3. The d...

Full description

Bibliographic Details
Main Authors: Uttam R. Pokharel, Aaron P. Naquin, Connor P. Brochon, Frank R. Fronczek
Format: Article
Language:English
Published: International Union of Crystallography 2020-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
1,1′-bis(pyridyltriazoylmethyl)ferrocene
crystal structure
click reaction
tetradentate ligand
disubstituted ferrocene
copper(i) complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020011901

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989020011901

Similar Items