1,7-Sigmatropic rearrangement in 1,2-dihydro and 1,2,3,4-tetrahydroquinoline synthesis using marine sponge/H2C2O4 as a catalyst

Marine sponge/oxalic acid was found to be an efficient catalyst for the imino Diels–Alder reaction of synthesized N-aryl-substituted aldimines and various alkenes to provide 1,2-dihyro and 1,2,3,4-tetrahydro-quinolines using 1,7-sigmatropic rearrangement with induction of chirality. Mild reaction co...

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Bibliographic Details
Main Authors: Mohammad Reza Shushizadeh, Azar Mostoufi, Abdol-azim Behfar, Minoo Heidary
Format: Article
Language:English
Published: Elsevier 2015-11-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535212001451