Bipyrrole boomerangs via Pd-mediated tandem cyclization–oxygenation. Controlling reaction selectivity and electronic properties

Boomerang-shaped bipyrroles containing donor–acceptor units were obtained through a tandem palladium-mediated reaction consisting of a cyclization step, involving double C–H bond activation, and a double α-oxygenation. The latter reaction can be partly suppressed for the least reactive systems, prov...

Full description

Bibliographic Details
Main Authors: Liliia Moshniaha, Marika Żyła-Karwowska, Joanna Cybińska, Piotr J. Chmielewski, Ludovic Favereau, Marcin Stępień
Format: Article
Language:English
Published: Beilstein-Institut 2020-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.16.81