[2 + 2] Photodimerization of Naphthylvinylpyridines through Cation-π Interactions in Acidic Solution

[2 + 2] Photodimerization of Naphthylvinylpyridines through Cation-π Interactions in Acidic Solution

Irradiation of (E)-4-(2-(2-naphthyl)vinyl)pyridine (1a) and (E)-4-(2-(1-naphthyl)vinyl)pyridine (1b) with a 250 W high-pressure mercury lamp in acidic solution afforded synHT dimers in high stereoselectivities. Similar results were obtained by visible light irradiation. On the other hand, when the r...

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Bibliographic Details
Main Authors: Shinji Yamada, Yuka Nojiri
Format: Article
Language:English
Published: MDPI AG 2017-03-01
Series:Molecules
Subjects:
cation-π interaction
[2 + 2] photodimerization
cyclobutane derivative
naphthylvinylpyridine
stereoselective reaction
Online Access:http://www.mdpi.com/1420-3049/22/3/491

Internet

http://www.mdpi.com/1420-3049/22/3/491

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