Organocatalyzed ring-opening copolymerization of α-bromo-γ-butyrolactone with ε-caprolactone for the synthesis of functional aliphatic polyesters – pre-polymers for graft copolymerization

Organocatalyzed ring-opening copolymerization of α-bromo-γ-butyrolactone with ε-caprolactone for the synthesis of functional aliphatic polyesters – pre-polymers for graft copolymerization

Diphenyl phosphate (DPP) was exploited as an organocatalyst to synthesize copolymers by ring-opening polymerization with α-bromo-γ-butyrolactone (αBrγBL) and ε-caprolactone (εCL) as monomers and polyethylene glycol (PEG) as initiator. The conversion rates of monomers and molecular weights of copolym...

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Bibliographic Details
Main Authors: Chen Gao, Chi-Hui Tsou, Chun-Yan Zeng, Li Yuan, Rui Peng, Xue-Mei Zhang
Format: Article
Language:English
Published: Taylor & Francis Group 2018-01-01
Series:Designed Monomers and Polymers
Subjects:
εCL
αBrγBL
DPP
ring-opening polymerization
ATRP
functional aliphatic polyester
Online Access:http://dx.doi.org/10.1080/15685551.2018.1550288

Internet

http://dx.doi.org/10.1080/15685551.2018.1550288

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