Fluorine-Substituted Arylphosphine for an NHC-Ni(I) System, Air-Stable in a Solid State but Catalytically Active in Solution

Fluorine-Substituted Arylphosphine for an NHC-Ni(I) System, Air-Stable in a Solid State but Catalytically Active in Solution

Monovalent NHC-nickel complexes bearing triarylphosphine, in which fluorine is incorporated onto the aryl groups, have been synthesized. Tris(3,5-di(trifluoromethyl)-phenyl)phosphine efficiently gave a monovalent nickel bromide complex, whose structure was determined by X-ray diffraction analysis fo...

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Bibliographic Details
Main Authors: Kouki Matsubara, Takahiro Fujii, Rion Hosokawa, Takahiro Inatomi, Yuji Yamada, Yuji Koga
Format: Article
Language:English
Published: MDPI AG 2019-09-01
Series:Molecules
Subjects:
monovalent nickel
fluorine-substituted phosphine
Kumada coupling
intermolecular interaction
DFT calculations
Online Access:https://www.mdpi.com/1420-3049/24/18/3222

Internet

https://www.mdpi.com/1420-3049/24/18/3222

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