Crystal structure of di-μ-hydroxido-κ4O:O-bis[bis(acetylacetonato-κ2O,O′)cobalt(III)]

Crystal structure of di-μ-hydroxido-κ4O:O-bis[bis(acetylacetonato-κ2O,O′)cobalt(III)]

The dinuclear title complex, [Co2(C5H7O2)4(μ-OH)2] or [Co(acac)2(μ-OH)]2, where acac is acetylacetonate, is centrosymmetric with half of the molecule per asymmetric unit. The molecular structure is a dimer of octahedrally coordinated CoIII atoms with four O atoms from two chelating acac ligands and...

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Bibliographic Details
Main Authors: Casseday P. Richers, Jeffery A. Bertke, Thomas B. Rauchfuss
Format: Article
Language:English
Published: International Union of Crystallography 2015-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cobalt(III)
acac ligand
bridging hydroxide ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015013663

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http://scripts.iucr.org/cgi-bin/paper?S2056989015013663

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