Derivatives of N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]ethanediamide

Derivatives of N,N'-bis[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]ethanediamide

Compound, [(HOCH2)3CNHC(O)]2 (1), obtained from (HOCH2)3CNH2 and EtOC(O)C(O)OEt, reacts with aryl aldehydes, ArCHO, to give the symmetric bis-alkylidene derivatives, N,N'-bis(2-Ar-5-ROCH 2-1,3-dioxan-5-yl)ethanediamides 3 (Ar = Ph, p-MeC6H4 or p-MeOC6H4, R = H). A similar reaction with Me2CO pr...

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Bibliographic Details
Main Authors: Low John N., Milne Bruce F., Ross Jennifer-Nicola, Wardell James L.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2002-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
alkylidene formation
stannylation
oxymercuriation
X-ray crystallography
molecular mechanics
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200012

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200012

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