Calix[6]arene-based atropoisomeric pseudo[2]rotaxanes

Some examples of atropoisomeric pseudorotaxanes in which the isomerism arises by the different conformations adopted by the wheel are reported here. Upon threading hexahexyloxycalix[6]arene 1 with ammonium axles 2+ or 3+, bearing biphenyl or trifluoromethylbenzyl moieties, respectively, two atropois...

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Bibliographic Details
Main Authors: Carmine Gaeta, Carmen Talotta, Placido Neri
Format: Article
Language:English
Published: Beilstein-Institut 2018-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.14.186