Palladium-catalyzed Suzuki-Miyaura coupling of thioureas or thioamides

Alternative carbene precursors for metal-catalyzed cross coupling may expand the portfolio of methods for C-C bond construction. Here, the authors report a Suzuki−Miyaura coupling of Pd−carbene complexes formed by desulfurization of thioureas or thioamides and affording a broad array of amidinium sa...

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Bibliographic Details
Main Authors: Shaoyu Mai, Wendong Li, Xue Li, Yingwei Zhao, Qiuling Song
Format: Article
Language:English
Published: Nature Publishing Group 2019-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-13701-5