Cavity-Containing [Fe2L3]4+ Helicates: An Examination of Host-Guest Chemistry and Cytotoxicity

Cavity-Containing [Fe2L3]4+ Helicates: An Examination of Host-Guest Chemistry and Cytotoxicity

Two new di(2,2′-bipyridine) ligands, 2,6-bis([2,2′-bipyridin]-5-ylethynyl)pyridine (L1) and bis(4-([2,2′-bipyridin]-5-ylethynyl)phenyl)methane (L2) were synthesized and used to generate two metallosupramolecular [Fe2(L)3](BF4)4 cylinders. The ligands and cylinders were characterized using elemental...

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Bibliographic Details
Main Authors: Lynn S. Lisboa, Mie Riisom, Roan A. S. Vasdev, Stephen M. F. Jamieson, L. James Wright, Christian G. Hartinger, James D. Crowley
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-07-01
Series:Frontiers in Chemistry
Subjects:
iron(II)
helicate
cytotoxicity
host-guest chemistry
metallosupramolecular architectures
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.697684/full

Internet

https://www.frontiersin.org/articles/10.3389/fchem.2021.697684/full

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