Crystal structure of dichlorido(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)iron(III) hexafluoridophosphate

Crystal structure of dichlorido(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)iron(III) hexafluoridophosphate

The title compound, [FeCl2(C14H30N4)]PF6, contains Fe3+ coordinated by the four nitrogen atoms of an ethylene cross-bridged cyclam macrocycle and two cis chloride ligands in a distorted octahedral environment. In contrast to other similar compounds this is a monomer. Intermolecular C—H...Cl interact...

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Bibliographic Details
Main Authors: Neil L. Funwie, Amy N. Cain, Brian Z. Fanning, Serena A. Hageman, Malorie Mullens, Travis K. Roberts, Daniel J. Turner, Cammi N. Valdez, Robert W. Vaughan, Henok G. Ermias, Jon D. Silversides, Stephen J. Archibald, Timothy J. Hubin, Timothy J. Prior
Format: Article
Language:English
Published: International Union of Crystallography 2015-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
macrocycle
cross bridge
iron
cylam
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015015340

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http://scripts.iucr.org/cgi-bin/paper?S2056989015015340

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