Crystal structure of octakis(4-methoxypyridinium) bis(4-methoxypyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) bis[(4-methoxypyridine-κN)pentakis(thiocyanato-κN)ferrate(III)] hexakis(thiocyanato-κN)ferrate(III) with iron in three different octahedral coordination environments

Crystal structure of octakis(4-methoxypyridinium) bis(4-methoxypyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) bis[(4-methoxypyridine-κN)pentakis(thiocyanato-κN)ferrate(III)] hexakis(thiocyanato-κN)ferrate(III) with iron in three different octahedral coordination environments

The crystal structure of the title salt, (C6H8NO)8[Fe(NCS)4(C6H7NO)2][Fe(NCS)5(C6H7NO)]2[Fe(NCS)6], comprises three negatively charged octahedral FeIII complexes with different coordination environments in which the FeIII atoms are coordinated by a different number of thiocyanate anions and 4-methox...

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Bibliographic Details
Main Authors: Aleksej Jochim, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2018-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
ferrate complexes
4-methoxypyridine
iron thiocyanate
octahedral coordination
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018001883

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http://scripts.iucr.org/cgi-bin/paper?S2056989018001883

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