A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazoles in Catalytic Olefin Epoxidation

A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazoles in Catalytic Olefin Epoxidation

The molybdenum(0)-carbonyl-triazole complexes [Mo(CO)3(L)3] [L = 1,2,3-triazole (1,2,3-trz) or 1,2,4-triazole (1,2,4-trz)] have been prepared and examined as precursors to molybdenum(VI) oxide catalysts for the epoxidation of cis-cyclooctene. Reaction of the carbonyl complexes with the oxidant tert-...

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Bibliographic Details
Main Authors: Lucie S. Nogueira, Patrícia Neves, Ana C. Gomes, Tatiana A. Amarante, Filipe A. Almeida Paz, Anabela A. Valente, Isabel S. Gonçalves, Martyn Pillinger
Format: Article
Language:English
Published: MDPI AG 2018-12-01
Series:Molecules
Subjects:
molybdenum
carbonyl complexes
triazole
oxidative decarbonylation
epoxidation
Online Access:http://www.mdpi.com/1420-3049/24/1/105

Internet

http://www.mdpi.com/1420-3049/24/1/105

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