Polystyrene-Supported Acyclic Diaminocarbene Palladium Complexes in Sonogashira Cross-Coupling: Stability vs. Catalytic Activity

Polystyrene-Supported Acyclic Diaminocarbene Palladium Complexes in Sonogashira Cross-Coupling: Stability vs. Catalytic Activity

Two types of immobilized on the amino-functionalized polystyrene-supported acyclic diaminocarbene palladium complexes (ADC-PdII) are investigated under Sonogashira cross-coupling conditions. Depending on substituents in the diaminocarbene fragment immobilized ADC-PdII, systems are found to have diff...

Full description

Bibliographic Details
Main Authors: Vladimir N. Mikhaylov, Viktor N. Sorokoumov, Denis Martin Liakhov, Alexander G. Tskhovrebov, Irina A. Balova
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Catalysts
Subjects:
palladium
cross-coupling
Sonogashira coupling
carbene
polystyrene
catalyst activation
boomerang mechanism
carbodiimide
isocyanide
Online Access:http://www.mdpi.com/2073-4344/8/4/141

Internet

http://www.mdpi.com/2073-4344/8/4/141

Similar Items