Synthesis, Structures and Chemistry of the Metallaboranes of Group 4–9 with M<sub>2</sub>B<sub>5</sub> Core Having a Cross Cluster M–M Bond

Synthesis, Structures and Chemistry of the Metallaboranes of Group 4–9 with M<sub>2</sub>B<sub>5</sub> Core Having a Cross Cluster M–M Bond

In an attempt to expand the library of M<sub>2</sub>B<sub>5</sub> bicapped trigonal-bipyramidal clusters with different transition metals, we explored the chemistry of [Cp*WCl<sub>4</sub>] with metal carbonyls that enabled us to isolate a series of mixed-metal tun...

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Bibliographic Details
Main Authors: Ranjit Bag, Suvam Saha, Rosmita Borthakur, Bijan Mondal, Thierry Roisnel, Vincent Dorcet, Jean-François Halet, Sundargopal Ghosh
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Inorganics
Subjects:
chromaborane
metallaborane
mixed-metal cluster
molybdaborane
tungstaborane
Online Access:https://www.mdpi.com/2304-6740/7/3/27

Internet

https://www.mdpi.com/2304-6740/7/3/27

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