Crystal structures of diiodidobis[(1S,5S)-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3]palladium(IV) and dichlorido[(1S,5S)-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3](triphenylphosphane-κP)palladium(IV)

Crystal structures of diiodidobis[(1S,5S)-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3]palladium(IV) and dichlorido[(1S,5S)-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3](triphenylphosphane-κP)palladium(IV)

The molecular structures of the chiral title compounds, [Pd(C19H28N2)2I2], (I), and [Pd(C19H28N2)Cl2(C18H15P)], (II), show a distorted square-planar coordination around the PdII atoms with two halogenide (Hal) ligands each and two N-heterocyclic carbene (NHC) ligands in (I) or one NHC and one triphe...

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Bibliographic Details
Main Authors: Eduard Rais, Ulrich Flörke, René Wilhelm
Format: Article
Language:English
Published: International Union of Crystallography 2015-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
coordination compound
palladium complexes
NHC ligands
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015013055

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http://scripts.iucr.org/cgi-bin/paper?S2056989015013055

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