Thermally-Induced Spin Crossover and LIESST Effect in the Neutral [FeII(Mebik)2(NCX)2] Complexes: Variable-Temperature Structural, Magnetic, and Optical Studies (X = S, Se; Mebik = bis(1-methylimidazol-2-yl)ketone)

Thermally-Induced Spin Crossover and LIESST Effect in the Neutral [FeII(Mebik)2(NCX)2] Complexes: Variable-Temperature Structural, Magnetic, and Optical Studies (X = S, Se; Mebik = bis(1-methylimidazol-2-yl)ketone)

Two new iron(II) neutral complexes of bis(1-methylimidazol-2-yl)ketone (Mebik) with molecular formula [FeII(Mebik)2(NCS)2] (1) and [FeII(Mebik)2(NCSe)2] (2) have been synthesized and characterized by magnetic measurements, single-crystal X-ray diffraction, and solid state UV-vis spectroscopy. The te...

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Bibliographic Details
Main Authors: Siddhartha De, Lise-Marie Chamoreau, Hasnaa El Said, Yanling Li, Alexandrine Flambard, Marie-Laure Boillot, Subrata Tewary, Gopalan Rajaraman, Rodrigue Lescouëzec
Format: Article
Language:English
Published: Frontiers Media S.A. 2018-08-01
Series:Frontiers in Chemistry
Subjects:
spin crossover
iron(II) complexes
photomagnetism
DFT
B3LYP/B3LYP*
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2018.00326/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2018.00326/full

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