Switching the Local Symmetry from <i>D</i><sub>5h</sub> to <i>D</i><sub>4h</sub> for Single-Molecule Magnets by Non-Coordinating Solvents

Switching the Local Symmetry from <i>D</i><sub>5h</sub> to <i>D</i><sub>4h</sub> for Single-Molecule Magnets by Non-Coordinating Solvents

A solvent effect towards the performance of two single-molecule magnets (SMMs) was observed. The tetrahydrofuran and toluene solvents can switch the equatorial coordinated 4-Phenylpyridine (4-PhPy) molecules from five to four, respectively, in [Dy(O<sup>t</sup>Bu)<sub>2</sub>...

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Bibliographic Details
Main Authors: Xia-Li Ding, Qian-Cheng Luo, Yuan-Qi Zhai, Qian Zhang, Lei Tian, Xinliang Zhang, Chao Ke, Xu-Feng Zhang, Yi Lv, Yan-Zhen Zheng
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Inorganics
Subjects:
dysprosium
local symmetry
single-molecule magnets
magnetic relaxation
solvent effect
Online Access:https://www.mdpi.com/2304-6740/9/8/64

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https://www.mdpi.com/2304-6740/9/8/64

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