(2.2.2-Cryptand)potassium tetrakis(η2-ethylene)cobaltate(−I)
The title salt, [K(C18H36N2O6)][Co(C2H4)4], is one of only two known homoleptic ethylenemetalates. The cation and anion are well separated, which gives an unperturbed tetrahedral anion as is expected for a formally Co−I d10 metal center. The considerable elongation of the C=C bonds of...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812038287 |