Synthesis of an organic-soluble π-conjugated [3]rotaxane via rotation of glucopyranose units in permethylated β-cyclodextrin

Synthesis of an organic-soluble π-conjugated [3]rotaxane via rotation of glucopyranose units in permethylated β-cyclodextrin

We synthesized symmetrically insulated oligo(para-phenylene) and oligothiophene with a pseudo-linked [3]rotaxane structure by full rotation of glucopyranose units via a flipping (tumbling) mechanism in the π-conjugated guest having two permethylated β-cyclodextrin units at both ends. We also succeed...

Full description

Bibliographic Details
Main Authors: Jun Terao, Yohei Konoshima, Akitoshi Matono, Hiroshi Masai, Tetsuaki Fujihara, Yasushi Tsuji
Format: Article
Language:English
Published: Beilstein-Institut 2014-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
cross-coupling reaction
insulated π-conjugated molecule
oligothiophene
permethylated cyclodextrin
[3]rotaxane
Online Access:https://doi.org/10.3762/bjoc.10.297

Internet

https://doi.org/10.3762/bjoc.10.297

Similar Items