Radical Reactivity of Frustrated Lewis Pairs with Diaryl Esters

Radical Reactivity of Frustrated Lewis Pairs with Diaryl Esters

Summary: Advances in the chemistry of metal-free systems known as frustrated Lewis pairs (FLPs) has exposed new reactivity of the p-block elements, particularly in small-molecule activation and catalysis. Typically, the mode of activation by FLPs has been predicated on a heterolytic two-electron pro...

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Bibliographic Details
Main Authors: Yashar Soltani, Ayan Dasgupta, Theodore A. Gazis, Darren M.C. Ould, Emma Richards, Ben Slater, Katarina Stefkova, Vladimir Y. Vladimirov, Lewis C. Wilkins, Darren Willcox, Rebecca L. Melen
Format: Article
Language:English
Published: Elsevier 2020-02-01
Series:Cell Reports Physical Science
Subjects:
frustrated Lewis pair
radical
boron
phosphorus
substituted olefins
electron paramagnetic resonance spectroscopy
Online Access:http://www.sciencedirect.com/science/article/pii/S2666386420300035

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http://www.sciencedirect.com/science/article/pii/S2666386420300035

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