Control of branch formation in ethylene polymerization by a [Ni(h3-2-MeC3H4)(diimine)] PF6 / DEAC catalyst system
The polymerization of ethylene mediated by [Ni(eta³-2-MeC3H4){ArN=C(H)C(H)=NAr}] PF6, Ar = 2,6-C6H3iPr2 /DEAC catalyst precursor under mild reaction conditions (reaction temperature between -10 ºC and 25 ºC and ethylene pressure between 109 and 1520 kPa) yields high molecular weight branched polyeth...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2001-01-01
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| Series: | Journal of the Brazilian Chemical Society |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000100006 |