Two novel nanoscaled bismuth oxido clusters, [Bi38O45(OMc)22(C8H7SO3)2(DMSO)6(H2O)1.5]·2.5H2O and [Bi38O45(HSal)22(OMc)2(DMSO)15(H2O)]·DMSO·2H2O

Two novel nanoscaled bismuth oxido clusters, [Bi38O45(OMc)22(C8H7SO3)2(DMSO)6(H2O)1.5]·2.5H2O and [Bi38O45(HSal)22(OMc)2(DMSO)15(H2O)]·DMSO·2H2O

The synthesis of [Bi38O45(OMc)22(C8H7SO3)2(DMSO)6(H2O)1.5]·2.5H2O (1·2.5H2O) (OMc—methacrylate) and [Bi38O45(HSal)22(OMc)2(DMSO)15(H2O)]·DMSO·2H2O(2·DMSO·2H2O) (Hsal—salicylate) starting from [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O and sodium 4-vinylbenzenesulfonate and salicylic acid, respectively, is p...

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Bibliographic Details
Main Authors: Schlesinger Maik, Miersch Linda, Rüffer Tobias, Lang Heinrich, Mehring Michael
Format: Article
Language:English
Published: De Gruyter 2013-03-01
Series:Main Group Metal Chemistry
Subjects:
bismuth oxido cluster
methacrylate
organic-inorganic hybrid materials
salicylate
sulfonate
Online Access:https://doi.org/10.1515/mgmc-2012-0073

Internet

https://doi.org/10.1515/mgmc-2012-0073

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