Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex
A series of new fluorenylamido-ligated zirconium complexes bearing an electron-donating adamantyl group on the amido ligand were synthesized and characterized by elemental analysis, 1H NMR, and single crystal X-ray analysis. The coordination mode of the fluorenyl ligand to the zirconium metal was η3...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2017-11-01
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Series: | Polymers |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4360/9/11/632 |