Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex

Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex

A series of new fluorenylamido-ligated zirconium complexes bearing an electron-donating adamantyl group on the amido ligand were synthesized and characterized by elemental analysis, 1H NMR, and single crystal X-ray analysis. The coordination mode of the fluorenyl ligand to the zirconium metal was η3...

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Bibliographic Details
Main Authors:	Yanjie Sun, Shuhui Li, Takeshi Shiono, Zhengguo Cai
Format:	Article
Language:	English
Published:	MDPI AG 2017-11-01
Series:	Polymers
Subjects:	constrained geometry catalysts zirconium complex adamantyl substituent propylene polymerization syndiospecificity
Online Access:	https://www.mdpi.com/2073-4360/9/11/632

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