Self-assembled coordination thioether silver(I) macrocyclic complexes for homogeneous catalysis

The bis-ortho-thioether 9,10-bis[(o-methylthio)phenyl]anthracene was synthesized as a syn-atropisomer, as revealed by X-ray diffraction. This alkylaryl thioether ligand (L) formed different macrocyclic complexes by coordination with silver(I) salts depending on the nature of the anion: M2L2 for AgOT...

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Bibliographic Details
Main Authors: Zhen Cao, Aline Lacoudre, Cybille Rossy, Brigitte Bibal
Format: Article
Language:English
Published: Beilstein-Institut 2019-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.15.239