Synthesis and crystal structure of (1,4,7,10-tetraazacyclododecane-κ4N)(tetrasulfido-κ2S1,S4)manganese(II)

Synthesis and crystal structure of (1,4,7,10-tetraazacyclododecane-κ4N)(tetrasulfido-κ2S1,S4)manganese(II)

The title compound, [Mn(S4)(C8H20N4)], was accidentally obtained by the hydrothermal reaction of Mn(ClO4)2·6H2O, cyclen (cyclen = 1,4,7,10-tetraazacyclododecane) and Na3SbS4·9H2O in water at 413 K, indicating that polysulfide anions might represent intermediates in the synthesis of thiometallate com...

Full description

Bibliographic Details
Main Authors: Felix Danker, Christian Näther, Wolfgang Bensch
Format: Article
Language:English
Published: International Union of Crystallography 2020-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
polysulfide
manganese(ii)
discrete complex
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020002492

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989020002492

Similar Items