Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes

Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes

The synthesis of SmCl3(THF)3 from SmCl3.6H2O is described. The reaction of SmCl3(THF)3 with NaBH4 in dry THF gave white microcrystalline tris (tetrahydroborato) tris (tetrahydrofuran) samarium (III), Sm(BH4)3(THF)3. The vibrational and magnetic properties of Sm(BH4)3(THF)3 have been studied.

Bibliographic Details
Main Authors: Hossein Aghabozorg, Robabeh Alizadeh
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 1993-12-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
smcl3(thf)3
sm(bh4)3(thf)3
preparation
vibrational spectra
Online Access:http://www.ijcce.ac.ir/article_10394_87e89fa37c5b57cb93b75340637897eb.pdf

Internet

http://www.ijcce.ac.ir/article_10394_87e89fa37c5b57cb93b75340637897eb.pdf

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