Synthesis and Reactivity of Novel Boranes Derived from Bulky Salicylaldimines: The Molecular Structure of a Maltolato Compound

Synthesis and Reactivity of Novel Boranes Derived from Bulky Salicylaldimines: The Molecular Structure of a Maltolato Compound

Reductive amination of salicylaldehyde or 3,5-di-tert-butylsalicylaldehyde and 1-adamantylamine using NaBH4 gave the corresponding aminoalcohols in high yields. Subsequent addition of one equivalent of H3B·SMe2 to the aminoalcohols, with loss of two equivalents of dihydrogen, resulted in the format...

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Bibliographic Details
Main Authors: Jeremy L. Bourque, Stephen J. Geier, Christopher M. Vogels, Andreas Decken, Stephen A. Westcott
Format: Article
Language:English
Published: MDPI AG 2015-02-01
Series:Crystals
Subjects:
adamantylamine
adduct
borane
hydroboration
maltol
Online Access:http://www.mdpi.com/2073-4352/5/1/91

Internet

http://www.mdpi.com/2073-4352/5/1/91

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